Skip to Main content Skip to Navigation
Journal articles

A Versatile Iridium(III) Metallacycle Catalyst for the Effective Hydrosilylation of Carbonyl and Carboxylic Acid Derivatives

Abstract : A versatile iridium(III) metallacycle catalyses rapidly and selectively the reduction of a large array of challenging esters and carboxylic acids as well as various ketones and aldehydes. Reactions proceed with high yields at room temperature through hydrosilylation followed by desilylation. Whether the reaction of various aldehydes and ketones results exclusively in alcohols, the hydrosilylation of esters leads to alcohols or ethers depending on the type of substrate. Regarding the carboxylic acids, the nature of the reagent controls also the outcome of the hydrosilylation reaction, either alcohols or aldehydes being formed.
Document type :
Journal articles
Complete list of metadatas

Cited literature [41 references]  Display  Hide  Download

https://hal-upec-upem.archives-ouvertes.fr/hal-01715048
Contributor : Francine Agbossou Niedercorn <>
Submitted on : Monday, August 31, 2020 - 4:40:35 PM
Last modification on : Tuesday, November 24, 2020 - 2:18:20 PM

File

Manuscript_hal-01715048.pdf
Files produced by the author(s)

Identifiers

Citation

Yann Corre, Vincent Rysak, Xavier Trivelli, Francine Agbossou-Niedercorn, Christophe Michon. A Versatile Iridium(III) Metallacycle Catalyst for the Effective Hydrosilylation of Carbonyl and Carboxylic Acid Derivatives. European Journal of Organic Chemistry, Wiley-VCH Verlag, 2017, 2017 (32), pp.4820-4826. ⟨10.1002/ejoc.201700801⟩. ⟨hal-01715048⟩

Share

Metrics

Record views

267

Files downloads

28